Professor che pioneered the chemistry of reactive ruthenium - ligand multiple bonded complexes , which he subsequently used to elucidate the mechanisms of atom and group transfer reactions with organic substrates . he discovered a series of biomimetic chemical reactions applicable to the synthesis of pharmaceuticals and fine chemicals . he also pioneered the photochemistry of phosphorescent metal complexes and synthesized , by photochemical means , novel types of reactive molecules that exhibit unique properties and reactivities unreachable by ground state molecules 支教授創(chuàng)立活性釕多重鍵配合物化學(xué)并用于揭示原子和基團(tuán)向有機(jī)底物轉(zhuǎn)移的反應(yīng)機(jī)理開拓一系列可應(yīng)用于藥物合成和精細(xì)化學(xué)品合成的仿生物化學(xué)反應(yīng)創(chuàng)立磷光金屬配合物光化學(xué),并利用光化學(xué)方法合成具有基態(tài)分子所無法達(dá)到的特殊性質(zhì)和反應(yīng)性的新穎物種。
百科解釋
Group transfer reactions are pericyclic reactions where one pi bond is converted to one sigma bond, at the same time that a sigma bond migrates.